Prototyping a Laser Spectroscope

Materials are usually classified according to their physical and chemical properties. New technologies today are making the identification of materials increasingly simple, fast and reliable. Building on our earlier research in using spectroscopy and the physics of light to visually differentiate materials, we are now ready to ask: Can we make a laser-induced breakdown spectrometer, locally in Ghana?

Two physics teaching assistants from the University of Ghana signed on with AMP team to help us find out: Nutifafa Y. Doumon (who already participated in #ampqamp), with an MSc degree in Nanoscience from University of Groningen, in the Netherlands and Rodney Abugre, who recently graduated with an MPhil in Physics from University of Ghana.

Test experiment for material surface excitation with an incandescent light
Test experiment for material surface excitation with an incandescent light

We first reviewed existing technologies and later performed our own experiments. Materials were sourced from Agbogbloshie, since the device will be used to test scrap metal from that location.

The goal for our first three experiments was to investigate the laser excitation process of the material surfaces. Apparatus include: Laser light source, converging lens, sample holder and timer. In the laser excitation process we expect the electromagnetic energy of the laser light to be transformed into thermal energy inside the metal and this based on the amount of energy absorbed by the metal. In our experiment we tested this principle using red laser of power 1 mW & < 5 mW, and an incandescent light of power 100 W. From the test experiments, we conclude that due to low power output of the laser light available, we cannot obtain the desirable results from the experiment (See pre-lab here).

Test setup to study laser interaction with material's surface
Test setup to study laser interaction with material’s surface

The next step was to set up and calibrate the complete optical path with components such as, prism, diffraction grating,  laser source, lens, filters mirrors and a camera. In this optical system, our major need is to find a laser with high enough power output to help us obtain the correct spectrum through excitation process.

We will use this system to record the spectrum for the different materials, analyze them using MatLab software and compare results to literature.  In the latter stages, the Agbogbloshie community will be engaged in a workshop on spectroscopy.

The setup for laser alignment [top view]
The setup for laser alignment [top view]
The setup for laser alignment [view from laser source]
The setup for laser alignment [view from laser source]

Spectroscopy for 3E-materials ID

E-waste workers in Agbogbloshie determine material type based on experience: years of dismantling and disassembly, visual examination and use of magnets to identify ferrous metals. However, in order to improve recycling practices — including protecting workers from hazardous materials — more advanced methods are required for identifying 3E-materials (i.e. materials present in Electrical and Electronic Equipment).

For the past few months, AMP team has been researching one technology that can help — spectroscopy, which detects the wavelengths of light unique to each material. First, we built a paper spectroscope that enables us see various spectra of light. Other DIY projects we have tried include foldable mini-spectrometer, and cd spectrometer. We used the spectral workbench software to analyze some spectra of light from different sources we recorded. Some of the sources were white florescent, blue light and candle light.

blue fluo

The goal of this research is to build a spectroscope that enables us to analyze the elemental composition of scrap materials in Agbogbloshie. A promising technique for identifying chemical elemental composition of a sample is called Laser Induced Breakdown Spectroscopy (LIBS).  Another DIY project of interest to this research is the ramanpi spectrometer which is based on raman spectroscopy. These and other techniques will be explored to achieve the goals of our research.

Assembling of lamp holder
Assembling a lamp holder
Testing the paper spectroscope
Testing the paper spectroscope